Back
Full-text
Journal article

Alkoxy Hydrosilanes As Surrogates of Gaseous Silanes for Hydrosilylation of Alkenes.

  • Buslov I Laboratory of Inorganic Synthesis and Catalysis, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), ISIC-LSCI , BCH 3305, Lausanne 1015, Switzerland.
  • Keller SC Laboratory of Inorganic Synthesis and Catalysis, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), ISIC-LSCI , BCH 3305, Lausanne 1015, Switzerland.
  • Hu X Laboratory of Inorganic Synthesis and Catalysis, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), ISIC-LSCI , BCH 3305, Lausanne 1015, Switzerland.
  • 2016-04-06
Published in:
  • Organic letters. - 2016
Physical and Theoretical Chemistry
Organic Chemistry
Biochemistry
English Me2SiH2, MeSiH3, and SiH4 are gaseous and flammable silanes that are inconvenient to use in chemical reactions. Catalytic amounts of a nickel pincer complex and NaO(t)Bu are reported to allow the synthesis of alkyl hydrosilanes from alkenes and alkoxy hydrosilanes, leading to the replacement of Me2SiH2, MeSiH3, and SiH4 by Me2(MeO)SiH, Me(EtO)2SiH, and (MeO)3SiH in hydrosilylation reactions of alkenes. The scope and mechanism of the reactions are also described.
Language
  • English
Open access status
green
Identifiers
Persistent URL
https://fredi.hepvs.ch/global/documents/230750
Statistics
Document views: 23 File downloads:
  • Full-text: 0