Combined Electrical and Optical Characterization of Polydiacetylene.
Journal article

Combined Electrical and Optical Characterization of Polydiacetylene.

  • Girard-Reydet C Department of Physical Chemistry, University of Geneva , Quai Ernest Ansermet 30, 1211 Geneva 4, Switzerland.
  • Ortuso RD Department of Physical Chemistry, University of Geneva , Quai Ernest Ansermet 30, 1211 Geneva 4, Switzerland.
  • Tsemperouli M Department of Physical Chemistry, University of Geneva , Quai Ernest Ansermet 30, 1211 Geneva 4, Switzerland.
  • Sugihara K Department of Physical Chemistry, University of Geneva , Quai Ernest Ansermet 30, 1211 Geneva 4, Switzerland.
  • 2016-03-30
Published in:
  • The journal of physical chemistry. B. - 2016
English Polydiacetylene (PDA) is a conductive polymer that has mechanochromism. When the polymer is exposed to mechanical stresses, change in temperature (thermochromism), pH (ionochromism), and so forth, the structural perturbation can be seen by the change in its color. Although it presents interesting electrical and optical properties, the relationship between these signals has rarely been investigated. We studied the correlation between the electrical conductivity and the absorption spectra of PDA. Upon UV irradiation, PDA absorption spectra presented a blue shift, which coincided with the decrease in the electrical conductivity.
Language
  • English
Open access status
closed
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https://fredi.hepvs.ch/global/documents/149772
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